An electrometallurgical methods for the production of lead-calcium alloys

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Authors

Lukasko, James J.

Issue Date

1991

Type

Thesis

Language

en_US

Keywords

Alternative Electrochemical Process , Lead-calcium Alloys , Battery Anodes , Electrowinning Anodes , Alloy , Production Of Alloy , Electrowinning , Calcium Chloride , Electrowinning Cells , Potassium Chloride-calcium Chloride Molten-salt Eutectic Electrolyte , Molten Lead Cathode , Current Efficiency , Mackay Theses and Dissertations Grant Collection

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Abstract

An alternative electrochemical process for the production of lead-calcium alloys used in battery and electrowinning anodes was developed. Other methods for the production of the alloy, Pb3Ca, are costly, complex, and inefficient. The method entailed an electrowinning step. Calcium chloride was fed to the electrowinning cell with a potassium chloride-calcium chloride molten-salt eutectic electrolyte. The calcium was electrowon at 650 degrees Celsius into a molten lead cathode to 6.1 weight percent calcium with 94 percent current efficiency.

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Thesis Number: 2768.
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University of Nevada, Reno

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In Copyright(All Rights Reserved)

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