Synthesis and Characterization of 4-(Trifluoromethyl)-dibenzamide-benzoguanamine and Crystallographic Characterization of a p-Triflourobenzoic Acid Complex of Terbium(III)
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Authors
Walton, Mark D.
de Bettencourt-Dias, Ana
Issue Date
10/25/2014
Type
Article
Language
en_US
Keywords
Chemistry , Crystallography , Organic Chemistry , Synthetic Chemistry
Alternative Title
Abstract
A molecule that coordinates with lanthanide metal ions and luminesces under UV light, 4-(trifluoromethyl)- dibenzamide-benzoguanamine (4TFMDBBG), was synthesized in 61.2% yield. When complexed with europium and terbium, red and green luminescence, respectively, was observed under UV light. Crystals of the ligand were isolated and its crystal structure was determined. Further characterization by NMR and UV-Vis spectroscopy and mass-spectrometry were performed. Crystals of a metal complex of a side product were also isolated and its crystal structure was determined.
Description
Citation
Walton, Mark D, de Bettencourt-Dias, Ana. “Synthesis and Characterization of 4-(Trifluoromethyl)-dibenzamide-benzoguanamine and Crystallographic Characterization of a p-Triflourobenzoic Acid Complex of Terbium(III).” Nevada State Undergraduate Research Journal. V1:I1 Fall-2014. (2014). http://dx.doi.org/10.15629/6.7.8.7.5_1-1_F-2014_3.
Publisher
Associate Students of the University of Nevada (ASUN)
License
No Known Copyright
Journal
Volume
Issue
PubMed ID
ISSN
2375-4832