Lifetimes of bound excited states of Pt-

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Chartkunchand, K. C.
Kaminska, M.
Anderson, E. K.
Kristiansson, M. K.
Eklund, G.
Hole, O. M.
Nascimento, R. F.
Blom, M.
Bjorkhage, M.
Kallberg, A.

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2017

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Article

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Abstract

Measurements of the radiative lifetimes of the two excited states of the platinum anion Pt- are presented. Pt- ions stored in the cryogenic ion storage ring DESIREE were photodetached at different photon wavelengths and the resulting yield of neutral Pt measured as a function of time was recorded. Analysis of the neutral decay curves show a 2.54 +/- 0.10 s lifetime for the higher-lying 5d(10)6(s) S-2(1/2) excited state and a lifetime in the range of 50-200 ms for the lower- lying 5d(9)6(s)(2) D-2(3/2) excited state. This is the first study to report the lifetime of a bound anion excited state with an electron configuration different from that of the anion ground state.

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KC Chartkunchand et al 2017 J. Phys.: Conf. Ser. 875 022051

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Creative Commons Attribution 3.0 Unported

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